I'm a bit confused. In the post three up you said you had good control of the tail (proper response to rudder inputs?), but that the tail was not holding well. In this one you say when you get good head speed the tail is good (which I take to mean it holds well), but if you give a lot of tail movement (rudder input?) it starts spinning (uncontrolled, ie it does not hold when you let up the rudder input).
1) Can you get it spun up? Note that spinning up on slick surfaces will result in some "spinning", especially if you try to spin up the head fast. During spin up putting the heli on a rougher surface will help the skids and/or tail fin grab the ground and keep it in place during spin up.
2) Can you hover it with little to no rudder input on the Tx? Does it hold properly?
3) If you give it a "pitch pump" with the collective/throttle does the tail hold position reasonably well (it may kick out a bit, up to 20 degrees, but more than that indicates a serious setup issue).
4) If you try to piroette the heli with rudder input does it go in the correct direction (right rudder result in the nose of the heli going right/clock-wise)? When yo recenter the rudder stick, does it stop and hold position?
Under which of these four scenarios will the heli start "spinning"?
If it is not #1 that is resulting in your spinning, then with that high of a gain setting it sounds like a mechanical problem.
1) Is the tail servo stripped at any point? With it powered down can you move the servo horn fully to each side with it being free and no sticking points or free spinning areas (might sound like gears are making poor contact, indicating a stripped spot)?
2) Is the tail rotor hub secure to the tail rotor shaft? The set screw is going into the flat (or dimple) on the shaft and is well centered (CW/CCW wise) on that flat?
3) If a TT system, the tail gears front and back are not loose on the shafts and the gears are making good mesh? The front gear is making good contact/mesh with the driving gear off the mainshaft?
4) If a belt system, the belt tension is tight enough? The pully has good teeth and is not slipping on the tail rotor shaft? The belt is in good condition? Good tooth rib depth along the whole belt?
The other possibility is a poor electrical connection from the Rx to the gyro to the servo. With it powered on (blades off!) wiggle the wire and connectors between these components and make sure the rudder doesn't make any odd movements and the gyro lights stay the same.